The Role of Nitrogen-Doped TiO₂ Supported by Platinum Catalyst Synthesized via Various Mode Preparations for Photocatalytic Enhancement

The limitations of TiO₂ as a photocatalyst such as the larger bandgap energy, which only activates under the UV region, give a lower photocatalytic activity. This study reports the role of the N and Pt co-dopant on the modification of the TiO₂ photocatalyst for photocatalytic degradation of methylene blue dye under different mode preparations, i.e., sequential and vice-versa modes. The sequential mode preparation of the N and Pt co-dopant TiO₂ photocatalyst consisted of the initial preparation of the N-doped TiO₂ (N-TiO₂) under the calcination method, which was then further doped with platinum (Pt) through the photodeposition process labeled as NP_seq-TiO₂, while the vice-versa mode was labeled as PN_rev-TiO₂. About 1.58 wt.% of N element was found in the NP_seq-TiO₂ photocatalyst, while there was no presence of N element detected in PN_rev-TiO₂, confirmed through an elemental analyzer (CHNS-O) and (EDX) analysis. The optimum weight percentage of Pt for both modes was detected at about ±2.0 wt.%, which was confirmed by inductively coupled plasma-emission spectroscopy (ICP-OES). The photoactivity under methylene blue (MB) dye degradation of the NP_seq-TiO₂ photocatalyst was 2 and 1.5 times faster compared to the unmodified TiO₂ and PN_rev-TiO₂, where the photodegradation rates were, ca., 0.065 min^-1 and 0.078 min^-1, respectively. This was due to the N elements being incorporated with the TiO₂ lattice, which was proven by UV-Vis/DRS where the bandgap energy of NP_seq-TiO₂ was reduced from 3.2 eV to 2.9 eV. In addition, the N generated a stronger PL signal due to the formation of oxygen vacancies defects on the surface of the NP_seq-TiO₂ photocatalyst. The higher specific surface area as well as higher pore volume for the NP_seq-TiO₂ photocatalyst enhanced its photocatalytic activity. Moreover, the NP_seq-TiO₂ showed the lowest COD value, and it was completely mineralized after 7 h of light irradiation. The preparation order did not affect the Pt dopant but did for the N element. Therefore, it is significant to investigate different mode preparations of the N and Pt co-dopant for the modification of TiO₂ to produce a good-quality photocatalyst for photocatalytic study under the photodegradation of MB dye.