Ultrasonic method for the preparation of organic porphyrin nanoparticles

Molecules. 2009 Jan 12;15(1):280-7. doi: 10.3390/molecules15010280.

Abstract

We report the synthesis and optical properties of organic porphyrin nanoparticles with narrow size distribution and good dispersibility. Nanoparticles were produced by a combination of precipitation and sonication, termed the "ultrasonic method". The resulting [tetrakis(para-chlorophenyl)porphyrin]TClPP nanoparticles were stable in solution without precipitation for at least 30 days. No self aggregation of the constituent porphyrin chromophores was observed. The TClPP nanoparticles exhibited interesting optical properties, particularly a large bathochromic shift in the absorption spectra.

MeSH terms

  • Chemistry, Organic / methods*
  • Nanoparticles / chemistry*
  • Nanoparticles / ultrastructure
  • Optical Phenomena
  • Organic Chemicals / chemical synthesis*
  • Organic Chemicals / chemistry
  • Porphyrins / chemical synthesis*
  • Porphyrins / chemistry
  • Solutions
  • Solvents / chemistry
  • Sonication
  • Spectrometry, Fluorescence
  • Spectrophotometry, Ultraviolet
  • Time Factors
  • Ultrasonics*
  • Water / chemistry

Substances

  • Organic Chemicals
  • Porphyrins
  • Solutions
  • Solvents
  • Water