Enhanced Performance of Nanoporous Titanium Dioxide Solar Cells Using Cadmium Sulfide and Poly(3-hexylthiophene) Co-Sensitizers

This work reports the effect of co-sensitization of nanoporous titanium dioxide using Cadmium Sulfide (CdS) and poly(3-hexylthiophene) (P3HT) on the performance of hybrid solar cells. CdS nanolayer with different thicknesses was grown on Titanium Dioxide (TiO₂) nanoparticles by chemical bath deposition technique with varying deposition times. Both atomic force microscopy (AFM) and UV⁻Vis⁻NIR spectroscopy measurements of TiO₂ electrode sensitized with and without CdS layer confirm that the existence of CdS layer on TiO₂ nanoparticles. AFM images of CdS-coated TiO₂ nanoparticles show that the surface roughness of the TiO₂ nanoparticle samples decreases with increasing CdS deposition times. Current density⁻voltage and external quantum efficiency (EQE) measurements were carried out for corresponding solar cells. Both short circuit current density (J_SC) and fill factor were optimized at the CdS deposition time of 12 min. On the other hand, a steady and continuous increment in the open circuit voltage (V_OC) was observed with increasing CdS deposition time and increased up to 0.81 V when the deposition time was 24 min. This may be attributed to the increased gradual separation of P3HT and TiO₂ phases and their isolation at the interfaces. The higher V_OC of 0.81 V was due to the higher built-in voltage at the CdS⁻P3HT interface when compared to that at the TiO₂⁻P3HT interface. Optimized nanoporous TiO₂ solar cells with CdS and P3HT co-sensitizers showed external quantum efficiency (EQE) of over 40% and 80% at the wavelengths corresponding to strong absorption of the polymer and CdS, respectively. The cells showed an overall average efficiency of over 2.4% under the illumination of 70 mW/cm² at AM 1.5 condition.