The thermoelectric properties of poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl}), commonly known as PTB7 conducting polymer, were investigated for the first time by Rastegaralam et al. in 2017 [ Crystals 2017, 7, 292]. PTB7 showed higher electrical conductivity or Seebeck coefficient (or even both) and, hence, a higher thermoelectric power factor than a variety of organic semiconductors. Therefore, it is worth working more on this semiconductor to improve its thermoelectric figure of merit. In this work, for the first time the effect of cosolvents on the thermoelectric properties of PTB7 is investigated. PTB7 conducting polymer dissolved in chlorobenzene was treated with different solvents: N,N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), N-methyl-2-pyrrolidone (NMP), acetonitrile (AC), and 1,2-dichloroethane (DCE). Upon addition of DMF, DMSO, and NMP, a significant enhancement in the electrical conductivity of the samples accompanied by a reduction in the Seebeck coefficient occurred as a result of doping, while the use of AC and DCE led to simultaneous enhancement in the electrical conductivity and the Seebeck coefficient by increasing the mobility. The dopants used in this work are inexpensive, are easily available, and do not need to perform any synthesis process. The highest estimated figure of merit value obtained in this work without optimization is 0.1, which is of the highest values for organic thermoelectric materials.