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Page 1
Non-Innocent Methylene Linker in Bridged Lewis Pair Initiators.
Weger M, Grötsch RK, Knaus MG, Giuman MM, Mayer DC, Altmann PJ, Mossou E, Dittrich B, Pöthig A, Rieger B. Weger M, et al. Angew Chem Int Ed Engl. 2019 Jul 15;58(29):9797-9801. doi: 10.1002/anie.201902833. Epub 2019 Jun 12. Angew Chem Int Ed Engl. 2019. PMID: 31046187
Deprotonation usually occurs as an unwanted side reaction in the Lewis pair polymerization of Michael acceptors, for which the conjugated addition of the Lewis base to the acid-activated monomer is the commonly accepted initiation mechanism. ...
Deprotonation usually occurs as an unwanted side reaction in the Lewis pair polymerization of Michael acceptors, for which the conjug …
NADPH oxidase-derived H2O2 subverts pathogen signaling by oxidative phosphotyrosine conversion to PB-DOPA.
Alvarez LA, Kovačič L, Rodríguez J, Gosemann JH, Kubica M, Pircalabioru GG, Friedmacher F, Cean A, Ghişe A, Sărăndan MB, Puri P, Daff S, Plettner E, von Kriegsheim A, Bourke B, Knaus UG. Alvarez LA, et al. Proc Natl Acad Sci U S A. 2016 Sep 13;113(37):10406-11. doi: 10.1073/pnas.1605443113. Epub 2016 Aug 25. Proc Natl Acad Sci U S A. 2016. PMID: 27562167 Free PMC article.
Single-Site, Organometallic Aluminum Catalysts for the Precise Group Transfer Polymerization of Michael-Type Monomers.
Weger M, Giuman MM, Knaus MG, Ackermann M, Drees M, Hornung J, Altmann PJ, Fischer RA, Rieger B. Weger M, et al. Chemistry. 2018 Oct 9;24(56):14950-14957. doi: 10.1002/chem.201802075. Epub 2018 Sep 6. Chemistry. 2018. PMID: 30048018
The novel catalysts perform a precision polymerization of a broad variety of monomers, ranging from 2-isopropenyl-2-oxazoline to tert-butylmethacrylate and N,N-dimethylacrylamide. Additionally, extended Michael-type structures like 4-vinyl pyridine are accessible. Especial …
The novel catalysts perform a precision polymerization of a broad variety of monomers, ranging from 2-isopropenyl-2-oxazoline to tert-butylm …
End of Frustration: Catalytic Precision Polymerization with Highly Interacting Lewis Pairs.
Knaus MG, Giuman MM, Pöthig A, Rieger B. Knaus MG, et al. J Am Chem Soc. 2016 Jun 22;138(24):7776-81. doi: 10.1021/jacs.6b04129. Epub 2016 Jun 10. J Am Chem Soc. 2016. PMID: 27254134
Herein we report on the catalytic polymerization of diverse Michael-type monomers with high precision by using simple but highly active combinations of phosphorus-containing Lewis bases and organoaluminum compounds. ...With these main-group element Lewis acid base pairs, i …
Herein we report on the catalytic polymerization of diverse Michael-type monomers with high precision by using simple but highly acti …
11 results