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21-Hydroxypregnane 21-O-malonylation, a crucial step in cardenolide biosynthesis, can be achieved by substrate-promiscuous BAHD-type phenolic glucoside malonyltransferases from Arabidopsis thaliana and homolog proteins from Digitalis lanata.
Phytochemistry. 2021 Jul;187:112710. doi: 10.1016/j.phytochem.2021.112710. Epub 2021 Apr 28.
Phytochemistry. 2021.
PMID: 33930670
Knockout of Arabidopsis thaliana VEP1, Encoding a PRISE (Progesterone 5β-Reductase/Iridoid Synthase-Like Enzyme), Leads to Metabolic Changes in Response to Exogenous Methyl Vinyl Ketone (MVK).
Klein J, Ernst M, Christmann A, Tropper M, Leykauf T, Kreis W, Munkert J.
Klein J, et al. Among authors: tropper m.
Metabolites. 2021 Dec 23;12(1):11. doi: 10.3390/metabo12010011.
Metabolites. 2021.
PMID: 35050133
Free PMC article.
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