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Copper(I) Iodide Catalyzed [3 + 3] Annulation of Iodonium Ylides with Pyridinium 1,4-Zwitterionic Thiolates for the Synthesis of 1,4-Oxathiin Scaffolds.
Org Lett. 2023 Jul 7;25(26):4830-4834. doi: 10.1021/acs.orglett.3c01538. Epub 2023 Jun 26.
Org Lett. 2023.
PMID: 37358369
Free PMC article.
Intramolecular Interception of the Remote Position of Vinylcarbene Silver Complex Intermediates by C(sp(3) )-H Bond Insertion.
Díaz-Jiménez À, Monreal-Corona R, Poater A, Álvarez M, Borrego E, Pérez PJ, Caballero A, Roglans A, Pla-Quintana A.
Díaz-Jiménez À, et al.
Angew Chem Int Ed Engl. 2023 Jan 26;62(5):e202215163. doi: 10.1002/anie.202215163. Epub 2022 Dec 22.
Angew Chem Int Ed Engl. 2023.
PMID: 36345831
Free PMC article.
The trapping of the elusive vinylogous position of a vinyl carbene with an aliphatic C(sp(3) )-H bond has been achieved for the first time during a silver-catalyzed carbene/alkyne metathesis (CAM) process. ...Density functional theory (DFT) calculations unveil the reaction …
The trapping of the elusive vinylogous position of a vinyl carbene with an aliphatic C(sp(3) )-H bond has been achieved for the first …
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