Effect of Engineered Biomaterials and Magnetite on Wastewater Treatment: Biogas and Kinetic Evaluation

In this study, the principle of sustaining circular economy is presented as a way of recovering valuable resources from wastewater and utilizing its energy potential via anaerobic digestion (AD) of municipality wastewater. Biostimulation of the AD process was investigated to improve its treatability efficiency, biogas production, and kinetic stability. Addressing this together with agricultural waste such as eggshells (CE), banana peel (PB), and calcined banana peels (BI) were employed and compared to magnetite (Fe₃O₄) as biostimulation additives via 1 L biochemical methane potential tests. With a working volume of 0.8 L (charge with inoculum to substrate ratio of 3:5 v/v) and 1.5 g of the additives, each bioreactor was operated at a mesophilic temperature of 40 °C for 30 days while being compared to a control bioreactor. Scanning electron microscopy and energy dispersive X-ray (SEM/EDX) analysis was used to reveal the absorbent's morphology at high magnification of 10 kx and surface pore size of 20.8 µm. The results showed over 70% biodegradation efficiency in removing the organic contaminants (chemical oxygen demand, color, and turbidity) as well as enhancing the biogas production. Among the setups, the bioreactor with Fe₃O₄ additives was found to be the most efficient, with an average daily biogas production of 40 mL/day and a cumulative yield of 1117 mL/day. The kinetic dynamics were evaluated with the cumulative biogas produced by each bioreactor via the first order modified Gompertz and Chen and Hashimoto kinetic models. The modified Gompertz model was found to be the most reliable, with good predictability.