The studies on global pollutant mercury (Hg), which is of public concern due to its high toxicity and capacity to long-range transport via atmospheric circulation, is poorly characterized in wet deposition over the Nepal-Himalayas region. Therefore, in order to understand the concentration levels, spatial distribution and seasonal variation of total Hg, 333 precipitation samples were collected from south to north: Kathmandu (1314 m a.s.l.), Dhunche (2065 m a.s.l.), Dimsa (3078 m a.s.l.) and Gosainkunda (4417 m a.s.l.) characterized as urban, rural, remote forest and remote alpine sites, respectively, for over one-year period. The highest Hg concentration was found in Kathmandu comparable to the urban sites worldwide, and significantly lower concentrations at other three sites demonstrated similar levels as in rural and remote alpine sites worldwide. Higher wet deposition fluxes of 34.91 and 15.89 μg m-2 year-1 were found in Kathmandu and Dhunche respectively, due to higher precipitation amount. Clear and distinct seasonal differences were observed with higher concentrations in non-monsoon and lower values in monsoon periods due to less scavenging and high pollutant concentration loadings during the dry period. The positive correlation of Hg flux and precipitation amount with Hg concentration suggested that both precipitation amount and Hg concentration plays a vital role in Hg deposition in the central Himalayan region. Enrichment factor (EFHg) indicated that the anthropogenic emission sources play a significant role for Hg enrichment and a high ratio of EFmonsoon to EFnon-monsoon (>2.18) suggested that the anthropogenic atmospheric mercury could likely be long-range transported from south Asian regions to the Himalayas during the monsoon season. In addition, our results showed that the major ionic compositions (e.g., SO42-, NO3-, NH4+, K+, Ca2+) could influence Hg concentration in wet precipitation. The anthropogenic sources of Hg such as biomass and fossil fuel combustion, crustal aerosols may contribute to the Hg concentration in wet precipitation over the central Himalayas.
Keywords: Central Himalayas; Mercury; South Asia; Spatial distribution; Wet deposition.
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