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An osmium(III)/osmium(V) redox couple generating Os(V)(O)(OH) center for cis-1,2-dihydroxylation of alkenes with H2O2: Os complex with a nitrogen-based tetradentate ligand.
J Am Chem Soc. 2012 Nov 21;134(46):19270-80. doi: 10.1021/ja309566c. Epub 2012 Nov 13.
J Am Chem Soc. 2012.
PMID: 23113538
Synthesis and properties of oxo-carboxylato- and dioxo-bridged diosmium complexes of tris(2-pyridylmethyl)amine.
Sugimoto H, Kitayama K, Ashikari K, Matsunami C, Ueda N, Umakoshi K, Hosokoshi Y, Sasaki Y, Itoh S.
Sugimoto H, et al. Among authors: kitayama k.
Inorg Chem. 2011 Sep 19;50(18):9014-23. doi: 10.1021/ic201230k. Epub 2011 Aug 9.
Inorg Chem. 2011.
PMID: 21827180
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