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Binuclear Ni(II) complexes containing ONS donor Schiff base ligands: Preparation, spectral characterization, X-ray crystallography and biological exploration.
Kalaiarasi G, Dharani S, Rajkumar SRJ, Lynch VM, Prabhakaran R. Kalaiarasi G, et al. J Inorg Biochem. 2020 Oct;211:111176. doi: 10.1016/j.jinorgbio.2020.111176. Epub 2020 Jul 18. J Inorg Biochem. 2020. PMID: 32730983
Four binuclear Ni(II) complexes [[Ni(2)(H-DEAsal-tsc)(2)(mu-dppm)].2Cl (1), [Ni(2)(DEAsal-mtsc)(2)(mu-dppm)] (2), [Ni(2)(DEAsal-etsc)(2)(mu-dppm)] (3) and [Ni(2)(DEAsal-ptsc)(2)(mu-dppm)] (4)] were synthesized from the ligands namely 4(N,N)-diethylaminosalicylaldehy …
Four binuclear Ni(II) complexes [[Ni(2)(H-DEAsal-tsc)(2)(mu-dppm)].2Cl (1), [Ni(2)(DEAsal-mtsc)(2)(mu-dppm)] (2), [Ni(2)(DEAsal-etsc)(2)(mu- …
Decolorization of safranin using Fissidens species and its ecotoxicological assessments: An in vitro and in silico approach.
Kiruthika T, Poonkothai M, Kalaiarasi K, Ajarem JS, Allam AA, Khim JS, Sudhakar C, Selvankumar T, Alaguprathana M. Kiruthika T, et al. Environ Res. 2022 Aug;211:113108. doi: 10.1016/j.envres.2022.113108. Epub 2022 Mar 18. Environ Res. 2022. PMID: 35314161
Maximum decolorization (95%) was recorded at initial pH of 6 with dye concentration of 20 mg/L, biosorbent dosage of 200 mg/L at 30 C and contact time of 2 days. Desorption studies revealed 0.1 N NaOH as the best desorbing agent with 92% recovery on third day. ...
Maximum decolorization (95%) was recorded at initial pH of 6 with dye concentration of 20 mg/L, biosorbent dosage of 200 mg/L at 30 C and co …
3-Acetyl-8-methoxy-2[H]-chromen-2-one derived Schiff bases as potent antiproliferative agents: Insight into the influence of 4(N)-substituents on the in vitro biological activity.
Kalaiarasi G, Rex Jeya Rajkumar S, Aswini G, Dharani S, Fronczek FR, Prabhakaran R. Kalaiarasi G, et al. Spectrochim Acta A Mol Biomol Spectrosc. 2018 Jul 5;200:246-262. doi: 10.1016/j.saa.2018.04.028. Epub 2018 Apr 14. Spectrochim Acta A Mol Biomol Spectrosc. 2018. PMID: 29694929
A series of 3-acetyl-8-methoxycoumarin appended thiosemicarbazones (1-4) was prepared from the reaction of 3-acetyl-8-methoxycoumarin with 4(N)-substituted thiosemicarbazides in a view of ascertaining their biological properties with the change of N-terminal substit …
A series of 3-acetyl-8-methoxycoumarin appended thiosemicarbazones (1-4) was prepared from the reaction of 3-acetyl-8-methoxycoumarin with 4 …
Experimental and theoretical charge density, intermolecular interactions and electrostatic properties of metronidazole.
Kalaiarasi C, George C, Gonnade RG, Hathwar VR, Poomani K. Kalaiarasi C, et al. Acta Crystallogr B Struct Sci Cryst Eng Mater. 2019 Dec 1;75(Pt 6):942-953. doi: 10.1107/S2052520619011272. Epub 2019 Oct 26. Acta Crystallogr B Struct Sci Cryst Eng Mater. 2019. PMID: 32830674
The experimental results have been compared with the corresponding periodic theoretical calculation performed at the B3LYP/6-31G** level using CRYSTAL09. The topological analysis reveals that the N-O and C-NO(2) exhibit less electron density as well as negative Laplacian o …
The experimental results have been compared with the corresponding periodic theoretical calculation performed at the B3LYP/6-31G** level usi …
An investigation on 3-acetyl-7-methoxy-coumarin Schiff bases and their Ru(ii) metallates with potent antiproliferative activity and enhanced LDH and NO release.
Kalaiarasi G, Jeya Rajkumar SR, Dharani S, Małecki JG, Prabhakaran R. Kalaiarasi G, et al. RSC Adv. 2018 Jan 4;8(3):1539-1561. doi: 10.1039/c7ra12104k. eCollection 2018 Jan 2. RSC Adv. 2018. PMID: 35540910 Free PMC article.
The analysis showed that the ligands have undergone C-H activation at the C(4) carbon of the pyrone ring and acted in a tridentate fashion by binding through C, N and S atoms. CT-DNA and protein (BSA/HSA) binding studies were carried out to analyze their interaction with b …
The analysis showed that the ligands have undergone C-H activation at the C(4) carbon of the pyrone ring and acted in a tridentate fashion b …
Diode Laser Stapedotomy vs Conventional Stapedotomy in Otosclerosis: A Double-Blinded Randomized Clinical Trial.
Parida PK, Kalaiarasi R, Gopalakrishnan S. Parida PK, et al. Otolaryngol Head Neck Surg. 2016 Jun;154(6):1099-105. doi: 10.1177/0194599816635132. Epub 2016 Mar 15. Otolaryngol Head Neck Surg. 2016. PMID: 26980905 Clinical Trial.
RESULTS: Sixty primary stapedotomies (30 in the CMS group and 30 in the DLS group) done for 60 patients (male, n = 42; female, n = 18) were included in the analysis. Preoperative mean air-bone (AB) gap in the DLS and CMS groups was 38.51 8.643 dB and 36.42 8.678 dB, …
RESULTS: Sixty primary stapedotomies (30 in the CMS group and 30 in the DLS group) done for 60 patients (male, n = 42; female, n …
Effect of combination of edible oils on blood pressure, lipid profile, lipid peroxidative markers, antioxidant status, and electrolytes in patients with hypertension on nifedipine treatment.
Sudhakar B, Kalaiarasi P, Al-Numair KS, Chandramohan G, Rao RK, Pugalendi KV. Sudhakar B, et al. Saudi Med J. 2011 Apr;32(4):379-85. Saudi Med J. 2011. PMID: 21483997
METHODS: In this study, patients were separated into 4 groups. Normal (n=14), hypertensive patients (n=38), 38 patients under medication with nifedipine were divided into 2 groups nifedipine control (n=12) and nifedipine + oil combination (sesame + sunflower …
METHODS: In this study, patients were separated into 4 groups. Normal (n=14), hypertensive patients (n=38), 38 patients under …
Estimation of Excited State Dipolemoments from Solvatochromic Shifts-Effect of pH.
Jayabharathi J, Kalaiarasi V, Thanikachalam V, Jayamoorthy K. Jayabharathi J, et al. J Fluoresc. 2014 Mar;24(2):599-612. doi: 10.1007/s10895-013-1334-3. Epub 2014 Jan 9. J Fluoresc. 2014. PMID: 24402679
The fluorescence decays for the imidazole fit satisfactorily to a single exponential kinetics. The prototropic studies of N,N-dimethyl-4-(1,4,5-triphenyl-1H-imidazol-2-yl)naphthalen-1-amine (DTINA) reveal that two monocations [imidazole nitrogen protanated (MC1) and …
The fluorescence decays for the imidazole fit satisfactorily to a single exponential kinetics. The prototropic studies of N,N- …