An In-Situ Fabrication Method of ZnO and Other Zn(II) Compounds Containing Polypropylene Composites

Int J Mol Sci. 2023 Jan 25;24(3):2357. doi: 10.3390/ijms24032357.

Abstract

This study investigated the methods of preparation of zinc oxide-polypropylene nanocomposites and their antibacterial properties. Seven solutions with ZnO nanoparticles or zinc ions were formulated as a PP additive. Two methods of ZnO NPs syntheses were carried out: (1) a modified hydrothermal method where a water solution of zinc acetate dihydrate, PEI, and ammonia were mixed with a final pH 11; (2) a thermal decomposition of a water solution of zinc acetate in the presence of PEI and ammonia using a two-screw extruder. During the experiments, the influence of various amounts of particle stabilizer, heating of the solutions, and the temperatures of the syntheses were examined. As a result, the simultaneous crystallization of ZnO in the extrusion process confirmed this method's attractiveness from the application point of view. Fabricated PP-ZnO composite shows antibacterial properties against Staphylococcus aureus, Escherichia coli, and Klebsiella pneumoniae.

Keywords: antibacterial properties; nanoparticles; polypropylene composites; zinc oxide.

MeSH terms

  • Ammonia
  • Anti-Bacterial Agents / chemistry
  • Anti-Bacterial Agents / pharmacology
  • Escherichia coli
  • Microbial Sensitivity Tests
  • Polypropylenes
  • Water
  • Zinc
  • Zinc Acetate
  • Zinc Oxide* / chemistry
  • Zinc Oxide* / pharmacology

Substances

  • Zinc Oxide
  • Polypropylenes
  • Ammonia
  • Zinc
  • Zinc Acetate
  • Anti-Bacterial Agents
  • Water