Mapping the structural boundaries of quasiracemate fractional crystallization using 2-substituted diarylamides

Chem Commun (Camb). 2017 Apr 20;53(33):4601-4604. doi: 10.1039/c7cc01638g.

Abstract

Video-assisted hot stage polarized light microscopy of 55 quasienantiomeric pairs, constructed from 22 chiral diarylamides that systematically differ in topology, reveals the structural boundaries of molecular shape to supramolecular assembly.