Magnetophoretic Equilibrium of a Polydisperse Ferrofluid

Nanomaterials (Basel). 2021 Oct 26;11(11):2849. doi: 10.3390/nano11112849.

Abstract

The equilibrium concentration distribution of magnetic nanoparticles in a nonuniform magnetic field is studied theoretically. A linear current-carrying wire is used as a source of a nonuniform field. An exact solution for the concentration profile of a dilute monodisperse suspension is obtained within the framework of the continuous mass transfer theory. The applicability of this solution in a broad range of amperage values is tested using Langevin dynamics simulations. Obtained solution is also generalized for polydisperse suspensions. It is demonstrated that the particle size distribution in a polydisperse system strongly depends on the distance from the wire and in general does not coincide with the original distribution of a uniform suspension.

Keywords: diffusion; ferrofluid; magnetic nanoparticles; magnetophoresis; mass transfer; polydispersity.