Comparative Study of CoFe2O4 Nanoparticles and CoFe2O4-Chitosan Composite for Congo Red and Methyl Orange Removal by Adsorption

Claudia Maria Simonescu; Alina Tătăruş; Daniela Cristina Culiţă; Nicolae Stănică; Ioana Alexandra Ionescu; Bogdan Butoi; Ana-Maria Banici

doi:10.3390/nano11030711

Comparative Study of CoFe₂O₄ Nanoparticles and CoFe₂O₄-Chitosan Composite for Congo Red and Methyl Orange Removal by Adsorption

Nanomaterials (Basel). 2021 Mar 12;11(3):711. doi: 10.3390/nano11030711.

Authors

Claudia Maria Simonescu¹, Alina Tătăruş^{1

2}, Daniela Cristina Culiţă³, Nicolae Stănică³, Ioana Alexandra Ionescu², Bogdan Butoi⁴, Ana-Maria Banici⁴

Affiliations

¹ Department of Analytical Chemistry and Environmental Engineering, Faculty of Applied Chemistry and Materials Science, Politehnica University of Bucharest, Polizu Street, No. 1-7, District 1, 011061 Bucharest, Romania.
² National Research and Development Institute for Industrial Ecology, INCD ECOIND Bucuresti, 71-73 Drumul Podul Dambovitei Str., 060652 Bucharest, Romania.
³ Ilie Murgulescu Institute of Physical Chemistry, 202 Splaiul Independentei, 060021 Bucharest, Romania.
⁴ National Institute for Laser, Plasma and Radiation Physics, 077125 Măgurele, Romania.

Abstract

(1) Background: A comparative research study to remove Congo Red (CR) and Methyl Orange (MO) from single and binary solutions by adsorption onto cobalt ferrite (CoFe₂O₄) and cobalt ferrite-chitosan composite (CoFe₂O₄-Chit) prepared by a simple coprecipitation method has been performed. (2) Methods: Structural, textural, morphology, and magnetic properties of the obtained magnetic materials were examined by X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, N₂ adsorption-desorption analysis, Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), and magnetic measurements. The optimal operating conditions of the CR and MO removal processes were established in batch experiments. The mathematical models used to describe the processes at equilibrium were Freundlich and Langmuir adsorption isotherms. (3) Results: Cobalt ferrite-chitosan composite has a lower specific surface area (S_BET) and consequently a lower adsorption capacity than cobalt ferrite. CoFe₂O₄ and CoFe₂O₄-Chit particles exhibited a superparamagnetic behavior which enabled their efficient magnetic separation after the adsorption process. The research indicates that CR and MO adsorption onto prepared magnetic materials takes place as monolayer onto a homogeneous surface. According to Langmuir isotherm model that best fits the experimental data, the maximum CR/MO adsorption capacity is 162.68/94.46 mg/g for CoFe₂O₄ and 15.60/66.18 mg/g for CoFe₂O₄-Chit in single solutions. The results of the kinetics study revealed that in single-component solutions, both pseudo-first-order and pseudo-second-order kinetics models represent well the adsorption process of CR/MO on both magnetic adsorbents. In binary solutions, adsorption of CR/MO on CoFe₂O₄ better follows the pseudo-second-order kinetics model, while the kinetic of CR/MO adsorption on CoFe₂O₄-Chit is similar to that of the dyes in single-component solutions. Acetone and ethanol were successfully used as desorbing agents. (4) Conclusions: Our study revealed that CoFe₂O₄ and CoFe₂O₄-Chit particles are good candidates for dye-contaminated wastewater remediation.

Keywords: Congo Red; Methyl Orange; dye adsorption; isothermal study; kinetic study; magnetic adsorbents.