Forgotten fatty acids-Surface properties supply conclusive evidence for including carotenoic acids

Chem Phys Lipids. 2018 Nov:216:48-53. doi: 10.1016/j.chemphyslip.2018.09.001. Epub 2018 Sep 25.

Abstract

The term "fatty acids" is conceptually well defined with regard to fats, whose extent of saturation or unsaturation is precisely indicated in the content description of foodstuff. In contrast, the term "fatty acid" gives no hint of being associated with "soap" (Na and K salts of fatty acids). Fatty acids in edible fats or in cleaning soaps have one thing in common: they are colorless. The prevalence of colorless fats and unadulterated white soaps has ensured that fatty acids are not associated with color. However, colored conjugated polyunsaturated fatty acids do exist, occurring abundantly in nature or manufactured at large scale. We endeavor to extricate conjugated polyenoic acids from oblivion by Based on the presented results (alkalicarotenoates have similar surface properties to alkalicarboxylates, carotenoic acids react like carboxylic acids to lipids), we argue for inclusion of conjugated carotenoic acids in fatty acid inventories and organic chemistry textbooks. Carotenoic acids and -salts have outstanding qualities by combining visibility and traceability with biological activity.

Keywords: Aggregation; Amphiphiles surface analysis; Carboxylic acids; Carotenoids; Cesium; Conjugation; Fatty acids; Imaging agents; Lipids; Micelles; Phospholipids; Potassium; Sodium; Surfactants.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carotenoids / chemistry*
  • Fatty Acids / chemistry*
  • Molecular Structure
  • Surface Properties

Substances

  • Fatty Acids
  • carotenoic acid
  • Carotenoids