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Homogeneous versus supported ONN pincer-type gold and palladium complexes: catalytic activity.
del Pozo C, Debono N, Corma A, Iglesias M, Sánchez F. del Pozo C, et al. ChemSusChem. 2009 Jul 20;2(7):650-7. doi: 10.1002/cssc.200900045. Epub 2009 Jun 2. ChemSusChem. 2009. PMID: 19492364
The complexes, immobilized onto ordered mesoporous silica (MCM-41), are shown to be very active catalysts in the hydrogenation of prochiral olefins (98% ee was achieved with the heterogenized chiral Au(MCM-41) complex), hydrosilylation, and Suzuki and Heck C-C coupling rea …
The complexes, immobilized onto ordered mesoporous silica (MCM-41), are shown to be very active catalysts in the hydrogenation of prochiral …
Understanding sulfone behavior in palladium-catalyzed domino reactions with aryl iodides.
Alonso I, Alcamí M, Mauleón P, Carretero JC. Alonso I, et al. Chemistry. 2006 Jun 2;12(17):4576-83. doi: 10.1002/chem.200600164. Chemistry. 2006. PMID: 16596685
Unlike traditionally used acyclic 1,2-disubstituted alkenes, the reaction of alpha,beta-unsaturated phenyl sulfones with aryl iodides under Heck reaction conditions takes place mainly by means of a four-component domino process, involving one unit of the alkene and three u …
Unlike traditionally used acyclic 1,2-disubstituted alkenes, the reaction of alpha,beta-unsaturated phenyl sulfones with aryl iodides under …