Multi-Objective Optimization of Epoxy Resin Adhesive for Pavement Toughened by Self-Made Toughening Agent

Polymers (Basel). 2023 Apr 19;15(8):1946. doi: 10.3390/polym15081946.

Abstract

Epoxy resin adhesive for pavement is often insufficient in flexibility and toughness. Therefore, a new type of toughening agent was prepared to overcome this shortcoming. To achieve the best toughening effect of a self-made toughening agent on an epoxy resin adhesive, its ratio to the epoxy resin needs to be optimally selected. A curing agent, a toughening agent, and an accelerator dosage were chosen as independent variables. The epoxy resin's adhesive tensile strength, elongation at break, flexural strength, and flexural deflection were used as response values to establish a single-objective prediction model of epoxy resin mechanical property indexes. Response surface methodology (RSM) was used to determine the single-objective optimal ratio and analyze the effect of factor interaction on epoxy resin adhesive's performance indexes. Based on principal component analysis (PCA), multi-objective optimization was performed using gray relational analysis (GRA) to construct a second-order regression prediction model between the ratio and gray relational grade (GRG) to determine the optimal ratio and to validate it. The results showed that the multi-objective optimization using response surface methodology and gray relational analysis (RSM-GRA) was more effective than the single-objective optimization model. The optimal ratio of epoxy resin adhesive was 100 parts of epoxy resin, 160.7 parts curing agent, 16.1 parts toughening agent, and 3.0 parts accelerator. The measured tensile strength was 10.75 MPa, elongation at break was 23.54%, the bending strength was 6.16 MPa, and the bending deflection was 7.15 mm. RSM-GRA has excellent accuracy for epoxy resin adhesive ratio optimization and can provide a reference for the epoxy resin system ratio optimization design of complex components.

Keywords: asphalt pavement; epoxy resin; gray relational analysis; mechanical properties; pavement materials; response surface method; toughening agent.