Insight into n-CaO₂/SBC/Fe(II) Fenton-like system for glyphosate degradation: pH change, iron conversion, and mechanism

Glyphosate has significant adverse effects on creature and ecological balance. Therefore, the efficient treatment of glyphosate wastewater is of great significance. In this study, nano calcium peroxide (n-CaO₂) was loaded onto activated sludge biochar (SBC), and then Fe(II) was added to construct a Fenton-like system (n-CaO₂/SBC/Fe(II)). SBC played the role of both a dispersant and catalyst, which greatly improved the removal capability of glyphosate. The removal efficiency of glyphosate in the n-CaO₂/SBC/Fe(II) system was as high as 99.6%. The persistent free radicals (PFRs) on SBC can promote the conversion of Fe(III) to Fe(II) in the reaction system, and Fe(II) can be maintained at about 15 mg L^-1 until the reaction reached equilibrium. Due to the synergistic effect of Fe(II) hydrolysis and SBC catalysis, n-CaO₂/SBC/Fe(II) system can effectively remove glyphosate in a wide initial pH range (4.0-10.0), and the pH of the reaction system can be remained in a suitable environment (4.0-6.0) for Fenton-like reaction. Advanced oxidation and chemical precipitation were the main mechanisms for the removal of glyphosate. Most of glyphosate could be oxidized into H₂PO^-₄ anions by breaking the bonds of C-P and C-N, and the H₂PO^-₄ can be further adsorbed and bounded on the surface of the composites. This system overcomes the shortcomings of pH rising and Fe(III) precipitation in the CaO₂-based oxidation systems, and realizes the efficient and complete degradation for glyphosate.