A Green Synthesis of CoFe₂O₄ Decorated ZIF-8 Composite for Electrochemical Oxygen Evolution

Low-cost, sustainable hydrogen production requires noble metal-free electrocatalysts for water splitting. In this study, we prepared zeolitic imidazolate frameworks (ZIF) decorated with CoFe₂O₄ spinel nanoparticles as active catalysts for oxygen evolution reaction (OER). The CoFe₂O₄ nanoparticles were synthesized by converting agricultural bio-waste (potato peel extract) into economically valuable electrode materials. The biogenic CoFe₂O₄ composite showed an overpotential of 370 mV at a current density of 10 mA cm^-2 and a low Tafel slope of 283 mV dec^-1, whereas the ZIF@CoFe₂O₄ composite prepared using an in situ hydrothermal method showed an overpotential of 105 mV at 10 mA cm^-2 and a low Tafel slope of 43 mV dec^-1 in a 1 M KOH medium. The results demonstrated an exciting prospect of high-performance noble metal-free electrocatalysts for low-cost, high-efficiency, and sustainable hydrogen production.