Using lead isotopes and potentially toxic elements to trace pollutant sources in the northern region of Guanabara Bay, southeastern Brazil

Mar Pollut Bull. 2019 Jul:144:216-223. doi: 10.1016/j.marpolbul.2019.04.057. Epub 2019 May 16.

Abstract

Guanabara Bay (southeastern Brazil) is located in the metropolitan region of the Rio de Janeiro State and is being affected by high levels of anthropization. This work analyzes not only the concentrations of potentially toxic elements (PTEs), but also Pb stable isotopes to trace possible anthropogenic and natural sources of pollutants in the northern region of Guanabara Bay and the Suruí and Magé rivers. The Governador Island Channel, the regions to the north of Governador Island, north and west of Paquetá Island, and the Magé coast are most affected by PTEs. In the study area, high PTE concentrations result from both natural and anthropogenic sources. The main sources of metals include municipal solid waste incineration, atmospheric aerosols, and ore lead tailings, as indicated by Pb isotopes. This work shows that Pb stable isotopes, associated with metal contamination, can improve the assessment of estuarine environment quality.

Keywords: Coastal area; Enrichment factor; Environmental geochemistry; Pollution source; Sediments.

MeSH terms

  • Bays / chemistry*
  • Brazil
  • Environmental Monitoring / methods*
  • Geologic Sediments / chemistry*
  • Islands
  • Isotopes / analysis
  • Lead / analysis*
  • Metals, Heavy / analysis*
  • Rivers / chemistry
  • Water Pollutants, Chemical / analysis*

Substances

  • Isotopes
  • Metals, Heavy
  • Water Pollutants, Chemical
  • Lead