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Page 1
Disproportionation and Ligand Lability in Low Oxidation State Boryl-Tin Chemistry.
Zheng X, Crumpton AE, Protchenko AV, Heilmann A, Ellwanger MA, Aldridge S. Zheng X, et al. Chemistry. 2023 Feb 16;29(10):e202203395. doi: 10.1002/chem.202203395. Epub 2023 Jan 4. Chemistry. 2023. PMID: 36399407 Free PMC article.
A viable mechanism for this rearrangement is shown by quantum chemical studies to involve a vinylidene intermediate (analogous to the isolable germanium compound, (boryl)(2) Ge=Ge), which undergoes facile atom transfer to generate Sn(boryl)(2) and trinuclear [Sn(3) …
A viable mechanism for this rearrangement is shown by quantum chemical studies to involve a vinylidene intermediate (analogous to the isolab …
Orange Zinc Germanate with Metallic Ge-Ge Bonds as a Chromophore-Like Center for Visible-Light-Driven Water Splitting.
Qian L, Chen JF, Li YH, Wu L, Wang HF, Chen AP, Hu P, Zheng LR, Yang HG. Qian L, et al. Angew Chem Int Ed Engl. 2015 Sep 21;54(39):11467-71. doi: 10.1002/anie.201505988. Epub 2015 Aug 20. Angew Chem Int Ed Engl. 2015. PMID: 26291331
Structural characterizations and theoretical calculations together reveal that the origin of visible-light response can be attributed to the unusual metallic Ge-Ge bonds which act in a similar way to organic chromophores. ...
Structural characterizations and theoretical calculations together reveal that the origin of visible-light response can be attributed to the …
Designing Multiple Crystallization in Superlattice-like Phase-Change Materials for Multilevel Phase-Change Memory.
Zheng L, Song W, Song Z, Song S. Zheng L, et al. ACS Appl Mater Interfaces. 2019 Dec 11;11(49):45885-45891. doi: 10.1021/acsami.9b16876. Epub 2019 Dec 3. ACS Appl Mater Interfaces. 2019. PMID: 31749358
In the SLL films, a two-step phase change process is observed at elevated temperatures, which reveals the crystallization of Ge(40)Te(60) (GT) and an interface-dominated formation of Cr(2)Ge(2)Te(6) (CrGT). The bonding of Cr-Te and Ge-Ge is accompanied by the breaki …
In the SLL films, a two-step phase change process is observed at elevated temperatures, which reveals the crystallization of Ge(40)Te(60) (G …