Synthetic studies towards the ent-labdane diterpenoids: rearrangement of ent-halimanes

Isidro S Marcos; María J Sexmero; Felix A Hernández; Marta Corrales; Pilar Basabe; David Díez; Julio G Urones

doi:10.3390/11100792

Synthetic studies towards the ent-labdane diterpenoids: rearrangement of ent-halimanes

Molecules. 2006 Oct 24;11(10):792-807. doi: 10.3390/11100792.

Authors

Isidro S Marcos¹, María J Sexmero, Felix A Hernández, Marta Corrales, Pilar Basabe, David Díez, Julio G Urones

Affiliation

¹ Departamento de Química Orgánica, Universidad de Salamanca, Plaza de los Caídos 1-5, 37008 Salamanca, Spain. ismarcos@usal.es

Abstract

For the first time ent-labdanes have been synthetised starting from ent-halimic acid, following a route that is the reverse of the biosynthetic one leading to the former compounds.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Diterpenes / chemical synthesis*
Diterpenes / chemistry*
Glycosides / chemical synthesis
Glycosides / chemistry

Substances

Diterpenes
Glycosides
ent-halimic acid
ent-labdane diglycoside