Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation

Search Page

Filters

My NCBI Filters

Results by year

Table representation of search results timeline featuring number of search results per year.

Year Number of Results
1976 1
1979 1
1980 1
2006 1
2007 3
2008 1
2009 3
2012 2
2013 1
2014 2
2015 1
2016 2
2019 1
2021 2
2023 1
2024 0

Text availability

Article attribute

Article type

Publication date

Search Results

22 results

Results by year

Filters applied: . Clear all
Page 1
Hybrids of [FeFe]- and [NiFe]-H2ase Active Site Models.
Zhang F, Woods TJ, Rauchfuss TB. Zhang F, et al. Organometallics. 2023 Jul 10;42(13):1607-1614. doi: 10.1021/acs.organomet.3c00173. Epub 2023 Jun 16. Organometallics. 2023. PMID: 37928214 Free PMC article.
Hydrogen activation by biomimetic [NiFe]-hydrogenase model containing protected cyanide cofactors.
Manor BC, Rauchfuss TB. Manor BC, et al. J Am Chem Soc. 2013 Aug 14;135(32):11895-900. doi: 10.1021/ja404580r. Epub 2013 Jul 30. J Am Chem Soc. 2013. PMID: 23899049 Free PMC article.
Complexes of the type (CO)2(CN)2Fe(pdt)Ni(dxpe) (dxpe = dppe, 1; dxpe = dcpe, 2) bind the Lewis acid B(C6F5)3 (BAr(F)3) to give the adducts (CO)2(CNBAr(F)3)2Fe(pdt)Ni(dxpe), (1(BAr(F)3)2, 2(BAr(F)3)2). Upon decarbonylation using amine oxides, these add …
Complexes of the type (CO)2(CN)2Fe(pdt)Ni(dxpe) (dxpe = dppe, 1; dxpe = dcpe, 2) bind the Lewis acid B(C6F5)3 (BAr(F)3) to give the a …
The Duisburg birth cohort study: influence of the prenatal exposure to PCDD/Fs and dioxin-like PCBs on thyroid hormone status in newborns and neurodevelopment of infants until the age of 24 months.
Wilhelm M, Wittsiepe J, Lemm F, Ranft U, Krämer U, Fürst P, Röseler SC, Greshake M, Imöhl M, Eberwein G, Rauchfuss K, Kraft M, Winneke G. Wilhelm M, et al. Mutat Res. 2008 Jul-Aug;659(1-2):83-92. doi: 10.1016/j.mrrev.2007.11.002. Epub 2007 Nov 12. Mutat Res. 2008. PMID: 18093869 Review.
Multiple linear regression analysis was used to describe the association of PCDD/F and PCB in maternal blood or milk with the outcome measurements after adjustment for confounding. Blood levels (n=182) of WHO 2005 toxic equivalents (TEQ) (PCDD/F+PCB) were in the ran …
Multiple linear regression analysis was used to describe the association of PCDD/F and PCB in maternal blood or milk with the outcome …
Preparation and Protonation of Fe2(pdt)(CNR)6, Electron-Rich Analogues of Fe2(pdt)(CO)6.
Zhou X, Barton BE, Chambers GM, Rauchfuss TB, Arrigoni F, Zampella G. Zhou X, et al. Inorg Chem. 2016 Apr 4;55(7):3401-12. doi: 10.1021/acs.inorgchem.5b02789. Epub 2016 Mar 21. Inorg Chem. 2016. PMID: 26999632 Free PMC article.
Compounds 1 and 2 protonate with strong acids to give the expected mu-hydrides [H1](+) and [H2](+). In contrast, 3 protonates with [HNEt3]BAr(F)4 (pKa(MeCN) = 18.7) to give the aminocarbyne [Fe2(pdt)(CNMe)5(mu-CN(H)Me)](+) ([3H](+)). ...
Compounds 1 and 2 protonate with strong acids to give the expected mu-hydrides [H1](+) and [H2](+). In contrast, 3 protonates with [HNEt3]BA …
Redox activation of alkene ligands in platinum complexes with non-innocent ligands.
Boyer JL, Cundari TR, DeYonker NJ, Rauchfuss TB, Wilson SR. Boyer JL, et al. Inorg Chem. 2009 Jan 19;48(2):638-45. doi: 10.1021/ic8017248. Inorg Chem. 2009. PMID: 19138145
Treatment of Pt((t)BA(F)Ph)(COD) or Pt((t)BA(F)Ph)(nbd) with AgPF(6) afforded the imino-semiquinones [Pt((t)BA(F)Ph)(COD)]PF(6) or [Pt((t)BA(F)Ph)(nbd)]PF(6), respectively. ...The Pt((t)BA(F)Ph)(COD), [Pt((t)BA(F)Ph)(COD)]PF(6), Pt((t)BA( …
Treatment of Pt((t)BA(F)Ph)(COD) or Pt((t)BA(F)Ph)(nbd) with AgPF(6) afforded the imino-semiquinones [Pt((t)BA(F)Ph)(CO …
Synthetic Designs and Structural Investigations of Biomimetic Ni-Fe Thiolates.
Basu D, Bailey TS, Lalaoui N, Richers CP, Woods TJ, Rauchfuss TB, Arrigoni F, Zampella G. Basu D, et al. Inorg Chem. 2019 Feb 18;58(4):2430-2443. doi: 10.1021/acs.inorgchem.8b02991. Epub 2019 Feb 1. Inorg Chem. 2019. PMID: 30707014 Free PMC article.
The nickel(II) precursors include (i) nickel with tripodal ligands: Ni(PS(3))(-) and Ni(NS(3))(-) (PS(3)(3-) = tris(phenyl-2-thiolato)phosphine, NS(3)(3-) = tris(benzyl-2-thiolato)amine), (ii) traditional diphosphine-dithiolates, including chiral diphosphine R,R-DIPAMP, (iii) cat …
The nickel(II) precursors include (i) nickel with tripodal ligands: Ni(PS(3))(-) and Ni(NS(3))(-) (PS(3)(3-) = tris(phenyl-2-thiolato)phosph …
Hydride bridge in [NiFe]-hydrogenase observed by nuclear resonance vibrational spectroscopy.
Ogata H, Krämer T, Wang H, Schilter D, Pelmenschikov V, van Gastel M, Neese F, Rauchfuss TB, Gee LB, Scott AD, Yoda Y, Tanaka Y, Lubitz W, Cramer SP. Ogata H, et al. Nat Commun. 2015 Aug 10;6:7890. doi: 10.1038/ncomms8890. Nat Commun. 2015. PMID: 26259066 Free PMC article.
Presented here is direct evidence for a hydride bridge in the active site of the (57)Fe-labelled fully reduced Ni-R form of Desulfovibrio vulgaris Miyazaki F [NiFe]-hydrogenase. A unique 'wagging' mode involving H(-) motion perpendicular to the Ni(mu-H)(57)Fe plane was stu …
Presented here is direct evidence for a hydride bridge in the active site of the (57)Fe-labelled fully reduced Ni-R form of Desulfovibrio vu …
Homogeneous catalytic reduction of dioxygen using transfer hydrogenation catalysts.
Heiden ZM, Rauchfuss TB. Heiden ZM, et al. J Am Chem Soc. 2007 Nov 21;129(46):14303-10. doi: 10.1021/ja073774p. Epub 2007 Oct 25. J Am Chem Soc. 2007. PMID: 17958423
A CH2Cl2 solution under 0.30 atm of H2 and 0.13 atm of O2 converted to H2O in the presence of 1 and 10 mol % of H(OEt2)2BAr(F)4 (BAr(F)4- = B(C6H3-3,5-(CF3)2)4-). The formation of water from H2 was verified by 2H NMR for the reaction of D2 + O2. ...
A CH2Cl2 solution under 0.30 atm of H2 and 0.13 atm of O2 converted to H2O in the presence of 1 and 10 mol % of H(OEt2)2BAr(F)4 (BAr( …
22 results