It has long been claimed that the anion of the DES or IL is critical for controlling the redox properties of metal ions. In this study we investigate the effect of different salt anions on the copper redox properties and speciation, and compare that with the effect of the different solvent anions, when a single copper salt is used in a range of solvents. It is shown that the effect of the solvent anion is much more significant than that of the salt anion on the redox properties. It is also found that copper species remain the same copper tetrachloride species despite the starting salt. An exception is seen for the copper(I) salt, which makes linear dichloride species, as well as the copper(II) acetate system, which displays concentration dependence. When the anion of the ionic liquid is changed, the copper species change correspondingly with the coordinating strength of the solvent anion, leading to a greater difference in redox response, which is due to the different species present. Thus, these speciation differences can be used to modify the redox potentials in the solution.