Hybrid Superconducting-Ferromagnetic [Bi₂Sr₂(Ca,Y)₂Cu₃O10]0.99(La2/3Ba1/3MnO₃)0.01 Composite Thick Films

Materials (Basel). 2019 Mar 14;12(6):861. doi: 10.3390/ma12060861.

Abstract

We report here on the development of composite thick films exhibiting hybrid superconducting and ferromagnetic properties, produced through a low-cost, fast, and versatile process. These films were made of high Tc cuprate superconductor Bi₂Sr₂(Ca,Y)₂Cu₃O10 (with Y:Ca ratio of 5%) and ferromagnetic perovskite La2/3Ba1/3MnO₃, synthesized by melting-quenching annealing process on a MgO substrate. Curie temperature for La2/3Ba1/3MnO₃ was determined (~336 K ) by magnetic field assisted thermogravimetric analysis (TGA), while superconducting behavior of Bi₂Sr₂(Ca,Y)₂Cu₃O10/MgO films was observed through temperature-dependent resistance measurements. Superconducting features in our hybrid compound were corroborated by temperature-dependent resistivity and magnetic susceptibility.

Keywords: composite materials; ferromagnetism; manganites; superconductors; thick films.