Hydrochemical and isotopic studies providing a new functional model for the coastal aquifers in Douala Coastal Sedimentary Basin (DCSB)/Cameroon

A new conceptual model of the hydrogeological systems in Cameroon's Douala Coastal Sedimentary Basin (DCSB) was constructed. The model is based upon the basin's known geology, plus data from recent field campaigns that allowed the collection of rainwater and groundwater samples for analyses of stable isotopes (δ²H, δ¹⁸O, δ¹³C), radiogenic isotopes (³H, ¹⁴C), and water chemistry. Aquifer characteristics that were thereby deciphered include recharge, isotopic distributions, residence times, and mixing processes. Rainfall samples (mean δ¹⁸O = -2.0 ‰; mean δ²H = -6.80 ‰; weighted mean = -2.4 ‰ δ¹⁸O, -9.85 ‰ δ²H) scatter along two distinct lines, thus indicating that local rainfall events undergo processes during convective events, variability in humidity, amount effects, and seasonal variations. Stable isotope values of river water samples are close to the weighted mean of local precipitation, with some downstream enrichment. The Quaternary/Mio-Pliocene superficial aquifer system (depth < 70 m) and the intermediate Oligocene/Upper Eocene aquifer system (depth: 70 to 200 m) exhibit evidence of similar fractionation processes through an enrichment gradient of δ-values. The enrichment is more pronounced at the top of the superficial aquifer, which is very exposed to direct rainfall water infiltration, evaporation, and amount effects. The depth profiles of δ-values coupled to water chemistry and tritium contents, evidence leakage between (i) the superficial system's Quaternary alluvium sands and Mio-Pliocene sands; and (ii) the superficial and intermediate systems. Thus, the aquifers that contain modern, post nuclear groundwater are characterized by flow exchanges and direct recharge from rainfall events. In contrast, the Upper Eocene system has depleted δ-values and lower bicarbonate contents, suggesting not only that this system was recharged by rapid infiltration (with limited effect of evaporation), but that this recharge occurred during a cooler time in the past. The residence times (computed from ¹⁴C dates) indicate uncorrected ages ranging from hundreds to thousands of years.