Essential Oil Compositions of Pinus Species (P. contorta Subsp. contorta, P. ponderosa var. ponderosa, and P. flexilis); Enantiomeric Distribution of Terpenoids in Pinus Species

Molecules. 2022 Sep 2;27(17):5658. doi: 10.3390/molecules27175658.

Abstract

Pinus species are important in traditional medicine throughout their ranges, and pine essential oils are of interest in aromatherapy and as topical treatments. In this work, the leaf (needle) essential oils of Pinus ponderosa var. ponderosa and Pinus contorta subsp. contorta from Oregon and Pinus flexilis growing in Idaho, have been obtained by hydrodistillation and analyzed by gas chromatographic techniques. The leaf essential oil of P. ponderosa was dominated by β-pinene (21.5-55.3%), methyl chavicol (8.5-41.5%), α-pinene (3.6-9.6%), δ-3-carene (3.6-6.2%), and α-terpineol (1.4-5.3%). The major components of P. contorta essential oil were β-phellandrene (23.8%), terpinen-4-ol (11.0%). The essential oil of P. flexilis was dominated by α-pinene (37.1%), β-pinene (21.9%), bornyl acetate (12.8%), and camphene (8.5%). Chiral gas chromatography revealed the enantiomeric ratios of α-pinene and limonene to be variable, but (-)-β-pinene predominated in Pinus essential oils.

Keywords: chiral GC-MS; enantiomers; limber pine; monoterpenoids; ponderosa pine; shore pine.

MeSH terms

  • Aromatherapy*
  • Limonene
  • Oils, Volatile* / chemistry
  • Pinus* / chemistry
  • Terpenes

Substances

  • Oils, Volatile
  • Terpenes
  • Limonene

Grants and funding

This research received no external funding.