Elucidating the Role of Oxide-Oxide/Carbon Interfaces of CuO_x-CeO₂/C in Boosting Electrocatalytic Performance

Herein, we report the synthesis and bifunctional oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) activities of a CuO_x-CeO₂/C electrocatalyst (EC) with rich oxide-oxide and oxide-carbon interfaces. It not only demonstrates a smaller Tafel slope (65 mV dec^-1) and higher limiting current density (-5.03 mA cm^-2) but also exhibits an onset potential (-0.10 V vs Ag/AgCl) comparable to that of benchmark Pt/C. Besides undergoing the favorable direct four-electron ORR pathway, it unveils a loss of 23% of its initial current after 6 h of a stability test and a negative shift of 4 mV in the half-wave potential after the accelerated durability test compared to the corresponding current loss of 28% and negative shift of 20 mV for Pt/C. It also reveals remarkable OER activity in an alkaline medium with a low onset potential (0.20 V) and a smaller Tafel slope (177 mV dec^-1). The bifunctional ORR/OER activity of CuO_x-CeO₂/C EC can be ascribed to the synergistic effects, its unique structure with enriched oxygen vacancies owing to the presence of Ce⁴⁺/Ce³⁺, robust oxide-oxide and oxide-carbon heterointerfaces, and homogeneous dispersion of oxides over the carbon bed, which facilitates faster electronic conduction.