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warshel ester p. ester
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Darshel Ester P. Estor
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Why nature really chose phosphate.
Q Rev Biophys. 2013 Feb;46(1):1-132. doi: 10.1017/S0033583512000157. Epub 2013 Jan 15.
Q Rev Biophys. 2013.
PMID: 23318152
Free PMC article.
Review.
That is, the same charge-charge repulsion that makes phosphate ester hydrolysis so unfavorable also makes it possible to regulate, by exploiting the electrostatics. This means that phosphate ester hydrolysis can not only be turned on, but also be turned off, by fine …
That is, the same charge-charge repulsion that makes phosphate ester hydrolysis so unfavorable also makes it possible to regulate, by …
Dineopentyl phosphate hydrolysis: evidence for stepwise water attack.
Kamerlin SC, Williams NH, Warshel A.
Kamerlin SC, et al.
J Org Chem. 2008 Sep 19;73(18):6960-9. doi: 10.1021/jo801207q. Epub 2008 Aug 27.
J Org Chem. 2008.
PMID: 18729515
Phosphate ester hydrolysis is ubiquitous in biology, playing a central role in energy production, signaling, biosynthesis, and the regulation of protein function among other things. ...Our data show that the substrate-as-base mechanism is viable for phosphate ester …
Phosphate ester hydrolysis is ubiquitous in biology, playing a central role in energy production, signaling, biosynthesis, and the re …
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