Membrane and Films Based on Novel Crown-Containing Dyes as Promising Chemosensoring Materials

Materials (Basel). 2010 Dec 17;3(12):5293-5310. doi: 10.3390/ma3125293.

Abstract

This paper discusses several works on supramolecular systems such as monolayer and multilayer, polymer films of various crown-containing dyes, surface-active monomers and polymers. Design, production and investigation of the membrane nanostructures based on crown ethers is a rapidly developing field at the "junction" of materials sciences and nanotechnology. These nanostructures can serve as convenient models for studying the self-organization and molecular recognition processes at interfaces that are typical for biomembranes. Based on the results obtained for such structures by absorption and fluorescence spectroscopy, atomic force and Brewster-angle microscopy, surface pressure and surface potential isotherm measurements, the possibility of developing micro- and nanomaterials possessing a set of specified properties (including chemosensor, photochromic and photorefractive materials) is demonstrated.

Keywords: crown-containing dyes; fluorescence; ion-selectivity; membranes; monolayers; photosensitivity; polymer films.

Publication types

  • Review