Mythic dyes or mythic colour? New insight into the use of purple dyes on codices

Spectrochim Acta A Mol Biomol Spectrosc. 2019 May 15:215:133-141. doi: 10.1016/j.saa.2019.01.091. Epub 2019 Feb 23.

Abstract

The traditional knowledge concerning the use of Tyrian purple in Late Antique and Medieval purple codices - those precious biblical texts written with noble metal inks on parchment dyed or painted with purple colourants - is here updated in view of new analytical evidence. Recent literature reports the analysis carried out on some purple codices, suggesting that Tyrian purple has not, if ever, been used in their making. A large number of purple codices has been considered in this work to elucidate the nature of the purple colour. Results have been discussed within the frame of previous information, thus covering a vast majority of the purple codices presently identified. In most of the instances the use of less expensive dyes such as folium or orchil is suggested. Moreover, analytical results from a non-invasive spectroscopic approach have been definitely confirmed by micro-invasive surface-enhanced Raman analysis performed on micro samples of purple parchment taken from two 6th century codices.

Keywords: Folium; Late antiquity; Orchil; Purple codex; SERS; Tyrian purple.