Crystal structure of 2-hy-droxy-2-(2-oxo-cyclo-hept-yl)-2,3-di-hydro-1H-indene-1,3-dione

Acta Crystallogr E Crystallogr Commun. 2015 Sep 12;71(Pt 10):o715-6. doi: 10.1107/S2056989015016126. eCollection 2015 Oct 1.

Abstract

In the title compound, C16H16O4, the five-membered ring of the indene-1,3-dione unit adopts a twist conformation, whereas the seven-membered ring adopts a twist-chair conformation. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds, weak C-H⋯O hydrogen bonds and π-π stacking [centroid-to-centroid distance = 3.7373 (8) Å] into a three-dimensional supra-molecular architecture.

Keywords: crystal structure; hydrogen bonding; indene-1,3-dione; π–π stacking.