Highly Sensitive, Stretchable Pressure Sensor Using Blue Laser Annealed CNTs

Nanomaterials (Basel). 2022 Jun 21;12(13):2127. doi: 10.3390/nano12132127.

Abstract

A piezoresistive sensor is an essential component of wearable electronics that can detect resistance changes when pressure is applied. In general, microstructures of sensing layers have been adopted as an effective approach to enhance piezoresistive performance. However, the mold-casted microstructures typically have quite a thick layer with dozens of microscales. In this paper, a carbon microstructure is formed by blue laser annealing (BLA) on a carbon nanotube (CNT) layer, which changes the surface morphology of CNTs into carbonaceous protrusions and increases its thickness more than four times compared to the as-deposited layer. Then, the pressure sensor is fabricated using a spin-coating of styrene-ethylene-butylene-styrene (SEBS) elastomer on the BLA CNTs layer. A 1.32 µm-thick pressure sensor exhibits a high sensitivity of 6.87 × 105 kPa-1, a wide sensing range of 278 Pa~40 kPa and a fast response/recovery time of 20 ms, respectively. The stability of the pressure sensor is demonstrated by the repeated loading and unloading of 20 kPa for 4000 cycles. The stretchable pressure sensor was also demonstrated using lateral CNT electrodes on SEBS surface, exhibiting stable pressure performance, with up to 20% stretching.

Keywords: blue laser annealing (BLA); carbon nanotube (CNT); pressure sensor.

Grants and funding

This work was supported by the Technology Innovation Program (20011317, development of an adhesive material capable of morphing more than 50% for flexible devices with a radius of curvature of 1 mm or less) funded By the Ministry of Trade, Industry & Energy (MOTIE, Korea).