Reversible binding of water, methanol, and ethanol to a five-coordinate ruthenium(II) complex.
Ma ES, Patrick BO, James BR.
Ma ES, et al. Among authors: patrick bo.
Dalton Trans. 2013 Mar 28;42(12):4291-8. doi: 10.1039/c3dt32909g.
Dalton Trans. 2013.
PMID: 23344393
The known green, five-coordinate, square-pyramidal trans-RuCl(2)(P-N)(PPh(3)) complex reversibly binds water, MeOH and EtOH in the vacant coordination site in the solid state and in CH(2)Cl(2) solution to give pink adducts (P-N = o-diphenylphosphino-N,N'-dimethylaniline). …
The known green, five-coordinate, square-pyramidal trans-RuCl(2)(P-N)(PPh(3)) complex reversibly binds water, MeOH and EtOH in the va …