Abstract
Three kinds of molecular complexes based on tetrathiafulvalene (TTF) and dialkylviologens were prepared and their crystal structures elucidated. While TTF-dimethylviologen complex forms a mixed stack arrangement of donors and acceptors in its crystal structure, TTF donors aggregate with long alkyl groups by CH/pi and/or van der Waals interactions in a couple of TTF-heptylviologen complexes.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Chemistry / methods
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Crystallization
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Crystallography, X-Ray
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Heterocyclic Compounds / chemistry*
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Hydrogen Bonding
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Indicators and Reagents
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Models, Chemical
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Models, Molecular
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Molecular Conformation
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Molecular Structure
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Viologens / chemistry*
Substances
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Heterocyclic Compounds
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Indicators and Reagents
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Viologens
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tetrathiafulvalene