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Triangular Regulation of Cucurbit[8]uril 1:1 Complexes.
Combes S, Tran KT, Ayhan MM, Karoui H, Rockenbauer A, Tonetto A, Monnier V, Charles L, Rosas R, Viel S, Siri D, Tordo P, Clair S, Wang R, Bardelang D, Ouari O. Combes S, et al. J Am Chem Soc. 2019 Apr 10;141(14):5897-5907. doi: 10.1021/jacs.9b00150. Epub 2019 Mar 13. J Am Chem Soc. 2019. PMID: 30808163
At first sight, the radical nature of the guest was of prime importance in obtaining the triangles, and we focused on extending this concept to biradicals to get supramolecular hexaradicals. Two sodium ions were systematically observed by ESI-MS in trimer structures, and t …
At first sight, the radical nature of the guest was of prime importance in obtaining the triangles, and we focused on extending this concept …
EPR Studies of the Binding Properties, Guest Dynamics, and Inner-Space Dimensions of a Water-Soluble Resorcinarene Capsule.
Ayhan MM, Casano G, Karoui H, Rockenbauer A, Monnier V, Hardy M, Tordo P, Bardelang D, Ouari O. Ayhan MM, et al. Chemistry. 2015 Nov 9;21(46):16404-10. doi: 10.1002/chem.201502212. Epub 2015 Sep 25. Chemistry. 2015. PMID: 26403999
Nitroxide free radicals have been used to study the inner space of one of Rebek's water-soluble capsules. EPR and (1) H NMR spectroscopy, ESI-MS, and DFT calculations showed a preference for the formation of 1:2 complexes. ...
Nitroxide free radicals have been used to study the inner space of one of Rebek's water-soluble capsules. EPR and (1) H NMR spectroscopy, …