Abstract
The recently discovered novel concept of self-terminating, oxidative radical cyclizations, through which alkynes can be converted into carbonyl compounds under very mild reaction conditions using O-centered inorganic and organic radicals as oxidants, is described.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkynes / chemistry
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Cyclization
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Free Radicals / chemistry*
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Hydroxyl Radical / chemistry
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Models, Chemical
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Molecular Structure
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Nitrates / chemistry
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Oxidants / chemistry*
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Oxidation-Reduction
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Reactive Oxygen Species / chemistry
Substances
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Alkynes
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Free Radicals
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Nitrates
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Oxidants
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Reactive Oxygen Species
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Hydroxyl Radical