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Watching solvent friction impede ultrafast barrier crossings: a direct test of Kramers theory.
Anna JM, Kubarych KJ. Anna JM, et al. J Chem Phys. 2010 Nov 7;133(17):174506. doi: 10.1063/1.3492724. J Chem Phys. 2010. PMID: 21054050
These measurements facilitate a direct comparison with the widely adopted Kramers theory of condensed phase reaction kinetics, and for the first time avoid the significant complication of electronic excitation to probe directly in the time domain a ground electronic state …
These measurements facilitate a direct comparison with the widely adopted Kramers theory of condensed phase reaction kinetics, and fo …