Nickel-Electrocatalytic Decarboxylative Arylation to Access Quaternary Centers.
Laudadio G, Neigenfind P, Péter Á, Rubel CZ, Emmanuel MA, Oderinde MS, Ewing TE, Palkowitz MD, Sloane JL, Gillman KW, Ridge D, Mandler MD, Bolduc PN, Nicastri MC, Zhang B, Clementson S, Petersen NN, Martín-Gago P, Mykhailiuk P, Engle KM, Baran PS.
Laudadio G, et al.
Angew Chem Int Ed Engl. 2024 Feb 19;63(8):e202314617. doi: 10.1002/anie.202314617. Epub 2024 Jan 18.
Angew Chem Int Ed Engl. 2024.
PMID: 38181042
The role of pyridine additive as well as the mechanism of this reaction are interrogated through Cyclic Voltammetry studies, titration experiments, control reactions with Ni(0) and Ni(II)-complexes, and ligand optimization data. Those studies indicate that the formation of …
The role of pyridine additive as well as the mechanism of this reaction are interrogated through Cyclic Voltammetry studies, titration exper …