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Distinguishing Nitro vs Nitrito Coordination in Cytochrome c' Using Vibrational Spectroscopy and Density Functional Theory.
Nilsson ZN, Mandella BL, Sen K, Kekilli D, Hough MA, Moënne-Loccoz P, Strange RW, Andrew CR. Nilsson ZN, et al. Inorg Chem. 2017 Nov 6;56(21):13205-13213. doi: 10.1021/acs.inorgchem.7b01945. Inorg Chem. 2017. PMID: 29053273 Free PMC article.
In this study, we probed Fe(III) heme-nitrite coordination in Alcaligenes xylosoxidans cytochrome c' (AXCP), an NO carrier that excludes anions in its native state but that readily binds nitrite (K(d) 0.5 mM) following a distal Leu16 Gly mutation to remove distal steric co …
In this study, we probed Fe(III) heme-nitrite coordination in Alcaligenes xylosoxidans cytochrome c' (AXCP), an NO carrier that excludes ani …