Torrefaction and carbonization of refuse derived fuel: Char characterization and evaluation of gaseous and liquid emissions

Catarina Nobre; Octávio Alves; Andrei Longo; Cândida Vilarinho; Margarida Gonçalves

doi:10.1016/j.biortech.2019.121325

Torrefaction and carbonization of refuse derived fuel: Char characterization and evaluation of gaseous and liquid emissions

Bioresour Technol. 2019 Aug:285:121325. doi: 10.1016/j.biortech.2019.121325. Epub 2019 Apr 6.

Authors

Catarina Nobre¹, Octávio Alves², Andrei Longo¹, Cândida Vilarinho³, Margarida Gonçalves⁴

Affiliations

¹ MEtRICs, Mechanical Engineering and Resource Sustainability Center, Department of Sciences and Technology of Biomass, Faculty of Sciences and Technology, NOVA University of Lisbon, 2829-516 Caparica, Portugal.
² MEtRICs, Mechanical Engineering and Resource Sustainability Center, Department of Sciences and Technology of Biomass, Faculty of Sciences and Technology, NOVA University of Lisbon, 2829-516 Caparica, Portugal; VALORIZA, Research Center for Endogenous Resource Valorization, Polytechnic Institute of Portalegre, 7300-555 Portalegre, Portugal.
³ MEtRICs, Mechanical Engineering and Resource Sustainability Center, Mechanical Engineering Department, School of Engineering, University of Minho, 4804-533 Guimarães, Portugal.
⁴ MEtRICs, Mechanical Engineering and Resource Sustainability Center, Department of Sciences and Technology of Biomass, Faculty of Sciences and Technology, NOVA University of Lisbon, 2829-516 Caparica, Portugal; VALORIZA, Research Center for Endogenous Resource Valorization, Polytechnic Institute of Portalegre, 7300-555 Portalegre, Portugal. Electronic address: mmpg@fct.unl.pt.

PMID: 30991186
DOI: 10.1016/j.biortech.2019.121325

Abstract

Refuse derived fuel containing non-hazardous industrial wastes was subjected to torrefaction and carbonization in an industrial furnace. The RDF samples were heated at 300 °C and 400 °C, for 30 min, yielding solid products (chars) as well as gases and liquids. Proximate and ultimate composition, mineral composition, chlorine content and high heating value were determined for the original sample and the produced chars. Thermal treatment produced RDF chars with carbon contents of 61.6 and 80.2 wt%, and high heating values of 19.9 and 23.5 MJ/kg, that could be further upgraded by washing with water to reduce ash and chlorine concentrations and improve calorific value. Gas products were composed of carbon dioxide and carbon monoxide with minor amounts of hydrogen. Methane was only detected in the gas produced at 400 °C. The process generated liquid products rich in organic compounds that represent potential in further energy or material recovery.

Keywords: Carbonization; Lignocellulosic wastes; Liquid emissions; Refuse Derived Fuel (RDF); Torrefaction.

MeSH terms

Carbon
Chlorine
Garbage*
Gases
Heating
Refuse Disposal*

Substances

Gases
Chlorine
Carbon