Reductive Hydrogenation of Sulfido-Bridged Tantalum Alkyl Complexes: A Mechanistic Insight.
Carbó JJ, Gómez M, Hernández-Prieto C, Hernán-Gómez A, Martín A, Mena M, Puiggalí-Jou J, Ricart JM, Santamaría C.
Carbó JJ, et al.
Inorg Chem. 2023 Jul 3;62(26):10100-10109. doi: 10.1021/acs.inorgchem.3c00043. Epub 2023 Jun 15.
Inorg Chem. 2023.
PMID: 37319404
Free PMC article.
Hydrogenolysis of a series of alkyl sulfido-bridged tantalum(IV) dinuclear complexes [Ta(eta(5)-C(5)Me(5))R(mu-S)](2) [R = Me, nBu (1), Et, CH(2)SiMe(3), C(3)H(5), Ph, CH(2)Ph (2), p-MeC(6)H(4)CH(2) (3)] has led quantitatively to the Ta(III) tetrametallic sulfide cluster [ …
Hydrogenolysis of a series of alkyl sulfido-bridged tantalum(IV) dinuclear complexes [Ta(eta(5)-C(5)Me(5))R(mu-S)](2) [R = Me, nBu (1 …