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Migratory insertion of the R2P group into a nitrogen-nitrogen bond - a novel type of rearrangement in phosphorus-nitrogen ligand chemistry. 3. The rearrangement of triphosphinohydrazide ligand -N(PPh2)-N(PPh2)2 to triphosphazenide anion {[(Ph2P-N]2PPh2}- in the coordination sphere of divalent cobalt and nickel.
Sushev VV, Belina NV, Fukin GK, Kurskiy YA, Kornev AN, Abakumov GA. Sushev VV, et al. Among authors: kornev an. Inorg Chem. 2008 Apr 7;47(7):2608-12. doi: 10.1021/ic701954k. Epub 2008 Mar 4. Inorg Chem. 2008. PMID: 18318475
The first structurally characterized metal (kappa(2)N,P)-phosphinohydrazides: the key to understanding the intramolecular rearrangement R2P-NR'-NR'-M --> R'N=PR2-NR'-M. Metalloderivatives of diisopropylphosphinohydrazines: synthesis and properties.
Kornev AN, Belina NV, Sushev VV, Fukin GK, Baranov EV, Kurskiy YA, Poddelskii AI, Abakumov GA, Lönnecke P, Hey-Hawkins E. Kornev AN, et al. Inorg Chem. 2009 Jun 15;48(12):5574-83. doi: 10.1021/ic900135b. Inorg Chem. 2009. PMID: 19438251
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