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Understanding the Aldo-Enediolate Tautomerism of Glycolaldehyde in Basic Aqueous Solutions.
Azofra LM, Quesada-Moreno MM, Alkorta I, Avilés-Moreno JR, Elguero J, López-González JJ. Azofra LM, et al. Chemphyschem. 2015 Jul 20;16(10):2226-36. doi: 10.1002/cphc.201500139. Epub 2015 May 5. Chemphyschem. 2015. PMID: 25943252
Additionally, the formation of Z-enediolate forms takes place at basic pH, together with an increase in the concentration of aldehyde species, such as 2-oxoethan-1-olate, and a decrease in the concentrations of the hydrated aldehyde and dimeric forms. ...Finally, Raman spe …
Additionally, the formation of Z-enediolate forms takes place at basic pH, together with an increase in the concentration of aldehyde specie …
Unusual coordinating behavior by three non-steroidal anti-inflammatory drugs from the oxicam family towards copper(II). Synthesis, X-ray structure for copper(II)-isoxicam, -meloxicam and -cinnoxicam-derivative complexes, and cytotoxic activity for a copper(II)-piroxicam complex.
Cini R, Tamasi G, Defazio S, Hursthouse MB. Cini R, et al. J Inorg Biochem. 2007 Aug;101(8):1140-52. doi: 10.1016/j.jinorgbio.2007.04.015. Epub 2007 May 10. J Inorg Biochem. 2007. PMID: 17592742
Unexpectedly, cinnoxicam (HCIN=2-methyl-1,1-dioxido-3-[(pyridin-2-ylamino)carbonyl]-2H-1,2-benzothiazin-4-yl-(3-phenylacrylate)) produced [Cu(MBT)(2)(PPA)(2)] (MBT=3-(methoxycarbonyl)-2-methyl-2H-1,2-benzothiazin-4-olate 1,1-dioxide, PPA=3-phenyl-N-pyridin-2-ylacrylamide). …
Unexpectedly, cinnoxicam (HCIN=2-methyl-1,1-dioxido-3-[(pyridin-2-ylamino)carbonyl]-2H-1,2-benzothiazin-4-yl-(3-phenylacrylate)) produced [C …
The 1:1 cocrystals of the proton-transfer compound dilituric acid--phenylbiguanide monohydrate.
Portalone G, Colapietro M. Portalone G, et al. Acta Crystallogr C. 2007 Mar;63(Pt 3):o181-4. doi: 10.1107/S0108270107005483. Epub 2007 Feb 17. Acta Crystallogr C. 2007. PMID: 17339726
A proton-transfer compound, 1-phenylbiguanidium 5-nitro-2,6-dioxo-1,2,3,6-tetrahydropyrimidin-4-olate monohydrate, C(8)H(12)N(5)(+) x C(4)H(2)N(3)O(5)(-) x H(2)O, has been synthesized by a reaction between dilituric acid (5-nitro-2,4,6-trihydroxypyrimidine, Dilit) and phen …
A proton-transfer compound, 1-phenylbiguanidium 5-nitro-2,6-dioxo-1,2,3,6-tetrahydropyrimidin-4-olate monohydrate, C(8)H(12)N(5)(+) x …