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Activity-Dependent Photoaffinity Labeling of Metalloproteases.
Prely L, Klein T, Geurink PP, Paal K, Overkleeft HS, Bischoff R. Prely L, et al. Methods Mol Biol. 2017;1491:103-111. doi: 10.1007/978-1-4939-6439-0_8. Methods Mol Biol. 2017. PMID: 27778284
Metalloproteases, notably members of the matrix metalloprotease (MMP) and A Disintegrin And Metalloprotease (ADAM) families play crucial roles in tissue remodeling, the liberation of growth factors and cytokines from cell membranes (shedding) and cell-cell or cell-matrix i …
Metalloproteases, notably members of the matrix metalloprotease (MMP) and A Disintegrin And Metalloprotease (ADAM) families play cruc …
Theoretical study on the radical scavenging activity of gallic acid.
Molski M. Molski M. Heliyon. 2023 Jan 5;9(1):e12806. doi: 10.1016/j.heliyon.2023.e12806. eCollection 2023 Jan. Heliyon. 2023. PMID: 36691549 Free PMC article.
The global descriptors of the chemical activity: ionization potential IP, electron affinity EA, chemical potential mu, absolute electronegativity chi, molecular hardness eta and softness S, electrophilicity index omega, electro-donating omega(-), electro-accepting omega(+) powers …
The global descriptors of the chemical activity: ionization potential IP, electron affinity EA, chemical potential mu, absolute electronegat …
The cleavage of biglycan by aggrecanases.
Melching LI, Fisher WD, Lee ER, Mort JS, Roughley PJ. Melching LI, et al. Osteoarthritis Cartilage. 2006 Nov;14(11):1147-54. doi: 10.1016/j.joca.2006.05.014. Epub 2006 Jun 30. Osteoarthritis Cartilage. 2006. PMID: 16806997 Free article.
RESULTS: Both aggrecanase-1 and aggrecanase-2 are able to cleave bovine and human biglycan at a site within their central leucine-rich repeat regions. Cleavage occurs at an asparagine-cysteine bond within the fifth leucine-rich repeat. In contrast, the closely related prot …
RESULTS: Both aggrecanase-1 and aggrecanase-2 are able to cleave bovine and human biglycan at a site within their central leucine-rich repea …
Discovery of novel inhibitors of a disintegrin and metalloprotease 17 (ADAM17) using glycosylated and non-glycosylated substrates.
Minond D, Cudic M, Bionda N, Giulianotti M, Maida L, Houghten RA, Fields GB. Minond D, et al. J Biol Chem. 2012 Oct 19;287(43):36473-87. doi: 10.1074/jbc.M112.389114. Epub 2012 Aug 27. J Biol Chem. 2012. PMID: 22927435 Free PMC article.
A disintegrin and metalloprotease (ADAM) proteases are implicated in multiple diseases, but no drugs based on ADAM inhibition exist. ...Analysis of ADAM cognate substrates revealed that glycosylation is often present in the vicinity of the scissile bond …
A disintegrin and metalloprotease (ADAM) proteases are implicated in multiple diseases, but no drugs based on ADAM inhibition …
Density Functional Theory Studies on the Chemical Reactivity of Allyl Mercaptan and Its Derivatives.
Molski M. Molski M. Molecules. 2024 Jan 31;29(3):668. doi: 10.3390/molecules29030668. Molecules. 2024. PMID: 38338412 Free PMC article.
In particular, the thermodynamic descriptors (BDE, PA, ETE, AIP, PDE, and G(acidity)) and global descriptors of chemical activity (ionization potential (IP), electron affinity (EA), chemical potential (mu), absolute electronegativity (chi), molecular hardness (eta) and softness ( …
In particular, the thermodynamic descriptors (BDE, PA, ETE, AIP, PDE, and G(acidity)) and global descriptors of chemical activity (ionizatio …
Sites of aggrecan cleavage by recombinant human aggrecanase-1 (ADAMTS-4).
Tortorella MD, Pratta M, Liu RQ, Austin J, Ross OH, Abbaszade I, Burn T, Arner E. Tortorella MD, et al. J Biol Chem. 2000 Jun 16;275(24):18566-73. doi: 10.1074/jbc.M909383199. J Biol Chem. 2000. PMID: 10751421 Free article.
Importantly, we show that this cleavage occurs more efficiently than cleavage within the IGD at the Glu(373)-Ala(374) bond. Cleavage occurred preferentially at the KEEE(1667-1668)GLGS bond to produce both a 140-kDa COOH-terminal fragment and a 375-kDa fragment that …
Importantly, we show that this cleavage occurs more efficiently than cleavage within the IGD at the Glu(373)-Ala(374) bond. Cleavage …
Intramolecular Ring-Expansion Reaction (RER) and Intermolecular Coordination of In Situ Generated Cyclic (Amino)(aryl)carbenes (cAArCs).
Lorkowski J, Krahfuß M, Kubicki M, Radius U, Pietraszuk C. Lorkowski J, et al. Chemistry. 2019 Aug 27;25(48):11365-11374. doi: 10.1002/chem.201902630. Epub 2019 Aug 2. Chemistry. 2019. PMID: 31276243 Free PMC article.
Without any additional trapping reagent, in situ generation of 1,1-diphenylisoidolin-3-ylidenes does not lead to the isolation of these compounds, but to the reaction products of the insertion of the carbene carbon atom into an ortho C-H bond of a phenyl substituent, follo …
Without any additional trapping reagent, in situ generation of 1,1-diphenylisoidolin-3-ylidenes does not lead to the isolation of these comp …