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Use of binding energy by an RNA enzyme for catalysis by positioning and substrate destabilization.
Narlikar GJ, Gopalakrishnan V, McConnell TS, Usman N, Herschlag D. Narlikar GJ, et al. Proc Natl Acad Sci U S A. 1995 Apr 25;92(9):3668-72. doi: 10.1073/pnas.92.9.3668. Proc Natl Acad Sci U S A. 1995. PMID: 7731962 Free PMC article.
We have compared the binding and reactivity of a series of oligonucleotide substrates and products of the Tetrahymena ribozyme, which catalyzes a site-specific phosphodiester cleavage reaction: CCCUCUpA+G<-->CCCUCU-OH+GpA. The results suggest that this RNA enzyme, li …
We have compared the binding and reactivity of a series of oligonucleotide substrates and products of the Tetrahymena ribozyme, which cataly …