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Intramolecular Proton Transfer in the Hydrogen Oxalate Anion and the Cooperativity Effects of the Low-Frequency Vibrations: A Driven Molecular Dynamics Study.
Boutwell D, Pierre-Jacques D, Cochran O, Dyke J, Salazar D, Tyler C, Kaledin M. Boutwell D, et al. J Phys Chem A. 2022 Feb 3;126(4):583-592. doi: 10.1021/acs.jpca.1c09686. Epub 2022 Jan 20. J Phys Chem A. 2022. PMID: 35049313
Strong involvement of CO(2) and CCO bending and the CC stretching vibrations indicate that these large amplitude motions cause the shortening of the O...O distance and thus promote H(+) transfer to the other oxygen by bringing it over the 3.4 kcal/mol barrier. ...
Strong involvement of CO(2) and CCO bending and the CC stretching vibrations indicate that these large amplitude motions cause the shortenin …
RNA-dependent conversion of phosphoserine forms selenocysteine in eukaryotes and archaea.
Yuan J, Palioura S, Salazar JC, Su D, O'Donoghue P, Hohn MJ, Cardoso AM, Whitman WB, Söll D. Yuan J, et al. Proc Natl Acad Sci U S A. 2006 Dec 12;103(50):18923-7. doi: 10.1073/pnas.0609703104. Epub 2006 Dec 1. Proc Natl Acad Sci U S A. 2006. PMID: 17142313 Free PMC article.
Here, we provide evidence for a different route present in these domains of life that requires the tRNA(Sec)-dependent conversion of O-phosphoserine (Sep) to Sec. In this two-step pathway, O-phosphoseryl-tRNA(Sec) kinase (PSTK) converts Ser-tRNA(Sec) to Sep-tRNA(Sec …
Here, we provide evidence for a different route present in these domains of life that requires the tRNA(Sec)-dependent conversion of O …