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Bacterial translation machinery for deliberate mistranslation of the genetic code.
Vargas-Rodriguez O, Badran AH, Hoffman KS, Chen M, Crnković A, Ding Y, Krieger JR, Westhof E, Söll D, Melnikov S. Vargas-Rodriguez O, et al. Proc Natl Acad Sci U S A. 2021 Aug 31;118(35):e2110797118. doi: 10.1073/pnas.2110797118. Proc Natl Acad Sci U S A. 2021. PMID: 34413202 Free PMC article.
Theoretical study on the ring-opening of 1,3-disilacyclobutane and H2 elimination.
Badran I, Rauk A, Shi YJ. Badran I, et al. J Phys Chem A. 2012 Dec 6;116(48):11806-16. doi: 10.1021/jp3087122. Epub 2012 Nov 19. J Phys Chem A. 2012. PMID: 23145867
The reactions examined include 2 + 2 cycloreversion to form two silenes by either a concerted or a stepwise mechanism, 1,1-, 1,2-, and 1,3-H(2) elimination, and the ring-opening initiated by 1,2-H shift to form an open-chain 1,3-disilabut-1-ylidene, which undergoes …
The reactions examined include 2 + 2 cycloreversion to form two silenes by either a concerted or a stepwise mechanism, 1,1-, 1,2-, and 1,3- …
Promotion of exocyclic bond cleavages in the decomposition of 1,3-disilacyclobutane in the presence of a metal filament.
Badran I, Shi YJ. Badran I, et al. J Phys Chem A. 2015 Jan 29;119(4):590-600. doi: 10.1021/jp511716x. Epub 2015 Jan 20. J Phys Chem A. 2015. PMID: 25560235
The dominant pathway has been demonstrated to be the insertion of the cyclic 1,3-disilacyclobut-1-ylidene, generated by exocyclic Si-H bond rupture, into the Si-H bond in DSCB to form 1,1'-bis(1,3-disilacyclobutane) (174 amu). ...Other reactions operating in the rea …
The dominant pathway has been demonstrated to be the insertion of the cyclic 1,3-disilacyclobut-1-ylidene, generated by exocyclic Si-H …