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Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber.
Mottillo C, Friščić T. Mottillo C, et al. Molecules. 2017 Jan 17;22(1):144. doi: 10.3390/molecules22010144. Molecules. 2017. PMID: 28106754 Free PMC article. Review.
The interest in and commercialization of such materials has created a need for more efficient, environmentally-friendly routes for making coordination bonds. Solid-state coordination chemistry is a versatile greener alternative to conventional synthesis, offering quantitat …
The interest in and commercialization of such materials has created a need for more efficient, environmentally-friendly routes for making co …
Towards medicinal mechanochemistry: evolution of milling from pharmaceutical solid form screening to the synthesis of active pharmaceutical ingredients (APIs).
Tan D, Loots L, Friščić T. Tan D, et al. Chem Commun (Camb). 2016 Jun 14;52(50):7760-81. doi: 10.1039/c6cc02015a. Chem Commun (Camb). 2016. PMID: 27185190 Review.
This overview highlights the emergent area of mechanochemical reactions for making active pharmaceutical ingredients (APIs), and covers the latest advances in the recently established area of mechanochemical screening and synthesis of pharmaceutical solid forms, specifical …
This overview highlights the emergent area of mechanochemical reactions for making active pharmaceutical ingredients (APIs), and covers the …
Enzymatic depolymerization of highly crystalline polyethylene terephthalate enabled in moist-solid reaction mixtures.
Kaabel S, Therien JPD, Deschênes CE, Duncan D, Friščić T, Auclair K. Kaabel S, et al. Proc Natl Acad Sci U S A. 2021 Jul 20;118(29):e2026452118. doi: 10.1073/pnas.2026452118. Proc Natl Acad Sci U S A. 2021. PMID: 34257154 Free PMC article.
Enzymes are highly selective, renewable catalysts active at mild temperatures; however, they lack activity toward the more crystalline forms of PET commonly found in consumer plastics, requiring the energy-expensive melt-amorphization step of PET before enzymatic depolymerization …
Enzymes are highly selective, renewable catalysts active at mild temperatures; however, they lack activity toward the more crystalline forms …
Mechanochemical ring-opening metathesis polymerization: development, scope, and mechano-exclusive polymer synthesis.
Lee GS, Lee HW, Lee HS, Do T, Do JL, Lim J, Peterson GI, Friščić T, Kim JG. Lee GS, et al. Chem Sci. 2022 Sep 7;13(39):11496-11505. doi: 10.1039/d2sc02536a. eCollection 2022 Oct 12. Chem Sci. 2022. PMID: 36320385 Free PMC article.
Ruthenium-alkylidene initiated ring-opening metathesis polymerization has been realized under solid-state conditions by employing a mechanochemical ball milling method. ...Therefore, the solubility and miscibility of monomers and Ru-initiators are not limiting factors in …
Ruthenium-alkylidene initiated ring-opening metathesis polymerization has been realized under solid-state conditions by employing a m …
Redox-promoted associative assembly of metal-organic materials.
Glavinović M, Qi F, Katsenis AD, Friščić T, Lumb JP. Glavinović M, et al. Chem Sci. 2016 Jan 1;7(1):707-712. doi: 10.1039/c5sc02214b. Epub 2015 Oct 9. Chem Sci. 2016. PMID: 28791114 Free PMC article.
We develop an associative synthesis of metal-organic materials that combines solid-state metal oxidation and coordination-driven self-assembly into a one-step, waste-free transformation. ...
We develop an associative synthesis of metal-organic materials that combines solid-state metal oxidation and coordination-driven self …
Polymorphs and solid solutions: materials with new luminescent properties obtained through mechanochemical transformation of dicyanoaurate(I) salts.
Vainauskas J, Topić F, Arhangelskis M, Titi HM, Friščić T. Vainauskas J, et al. Faraday Discuss. 2023 Jan 5;241(0):425-447. doi: 10.1039/d2fd00134a. Faraday Discuss. 2023. PMID: 36222462
We report the use of mechano- and thermochemical methods to create new solid-state luminescent materials from well-known inorganic salts, potassium dicyanoaurate(I) KAu(CN)(2), and potassium dicyanocuprate(I) KCu(CN)(2). ...Milling of the simple salt KAu(CN)(2) in the pres …
We report the use of mechano- and thermochemical methods to create new solid-state luminescent materials from well-known inorganic sa …
Cold photo-carving of halogen-bonded co-crystals of a dye and a volatile co-former using visible light.
Borchers TH, Topić F, Christopherson JC, Bushuyev OS, Vainauskas J, Titi HM, Friščić T, Barrett CJ. Borchers TH, et al. Nat Chem. 2022 May;14(5):574-581. doi: 10.1038/s41557-022-00909-0. Epub 2022 Mar 31. Nat Chem. 2022. PMID: 35361911
The formation of co-crystals by the assembly of molecules with complementary molecular recognition functionalities is a popular strategy to design or improve a range of solid-state properties, including those relevant for pharmaceuticals, photo- or thermoresponsive materia …
The formation of co-crystals by the assembly of molecules with complementary molecular recognition functionalities is a popular strategy to …
Mechanochemical and solvent-free assembly of zirconium-based metal-organic frameworks.
Užarević K, Wang TC, Moon SY, Fidelli AM, Hupp JT, Farha OK, Friščić T. Užarević K, et al. Chem Commun (Camb). 2016 Feb 4;52(10):2133-6. doi: 10.1039/c5cc08972g. Chem Commun (Camb). 2016. PMID: 26696097 Free PMC article.
The frameworks form either by milling, or spontaneous self-assembly by simply exposing solid mixtures of reactants to organic vapour. The generated frameworks exhibit high porosity and catalytic activity in the hydrolysis of model nerve agents, on par with their solvotherm …
The frameworks form either by milling, or spontaneous self-assembly by simply exposing solid mixtures of reactants to organic vapour. …
Illuminating milling mechanochemistry by tandem real-time fluorescence emission and Raman spectroscopy monitoring.
Julien PA, Arhangelskis M, Germann LS, Etter M, Dinnebier RE, Morris AJ, Friščić T. Julien PA, et al. Chem Sci. 2023 Oct 12;14(43):12121-12132. doi: 10.1039/d3sc04082h. eCollection 2023 Nov 8. Chem Sci. 2023. PMID: 37969588 Free PMC article.
In pursuit of accessible and interpretable methods for direct and real-time observation of mechanochemical reactions, we demonstrate a tandem spectroscopic method for monitoring of ball-milling transformations combining fluorescence emission and Raman spectroscopy, accompanied by …
In pursuit of accessible and interpretable methods for direct and real-time observation of mechanochemical reactions, we demonstrate a tande …
Mechanochemical methods for the transfer of electrons and exchange of ions: inorganic reactivity from nanoparticles to organometallics.
Fiss BG , Richard AJ , Douglas G , Kojic M , Friščić T , Moores A . Fiss BG , et al. Chem Soc Rev. 2021 Jul 21;50(14):8279-8318. doi: 10.1039/d0cs00918k. Epub 2021 Jun 4. Chem Soc Rev. 2021. PMID: 34085067
While the area has been extensively investigated and reviewed in the context of organic and solid-state supramolecular chemistry, less attention has been given to the recent advances in the context of inorganic transformations. ...
While the area has been extensively investigated and reviewed in the context of organic and solid-state supramolecular chemistry, les …
21 results